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12th Grade > Chemistry

PERIODIC CLASSIFICATION OF ELEMENTS MCQs

Total Questions : 30 | Page 2 of 3 pages
Question 11. Identify the least stable ion among the following.
  1.    Li−
  2.    Be−
  3.    B−
  4.    C−
 Discuss Question
Answer: Option B. -> Be−
:
B
Here we are going to compare these with each other and find out which is the least stable. But these species might not exist due to inherent instability.
Electronic configuration of Li - (2) fully-filled, so relatively more stable.
Be - (2,1) less stablethan Be (2);
B - (2,2) relatively stable;
C - (2,3) relatively stable.
Question 12. The atomic radius in case of inert gasses is?
  1.    Ionic radius
  2.    Covalent radius
  3.    Vander Waals radius
  4.    None
 Discuss Question
Answer: Option C. -> Vander Waals radius
:
C
As inert gasses do not combineto form molecules, they have VanderWaals radius.
Question 13. The ionization enthalpies of lithium and sodium are 520 kJ/mole and 495 kJ/mole respectively. The energies required to convert all the atoms present in 7 mg of lithium vapours and 23 mg of sodium vapours to their respective gaseous cations respectively are?
  1.    52 J, 49.5 J
  2.    520 J, 495 J
  3.    49.5 J, 52 J
  4.    495 J, 520 J
 Discuss Question
Answer: Option B. -> 520 J, 495 J
:
B
Number of moles of Li = 7×1037 = 103
Number of moles of Na= 23×10323 = 103
The amount of energy required for 1 mole of Li = 520 kJ.
For103 of Li = 250 ×103 = 520 J
The amount of energy required for 1 mole of Na = 495 kJ.
For103 of Na = 495 ×103 = 495 J
Question 14. The set representing the correct order of first ionization potential is?
  1.    K > Na > Li
  2.    Be > Mg > Ca
  3.    B > C > N
  4.    Ge > Si > C
 Discuss Question
Answer: Option B. -> Be > Mg > Ca
:
B
Down the group ionization enthalpy decreases with an increase in atomic size.
Along theperiod it increases due to an increase in effective nuclear charge and decrease in size.
K > Na > Li ---> same group, going upwards ---> so decreasing
Be > Mg > Ca ----> same groupbut going downwards, so it should increase.
B > C > N ---> same period, going left to right ---> so increasing
Ge > Si > C ----> same group, going upwards. ---> so decreasing
Question 15. For a given value of n (principal quantum number), ionization enthalpy is highest for
  1.    d - electrons 
  2.    f - electron
  3.    p - electron 
  4.    s - electron
 Discuss Question
Answer: Option D. -> s - electron
:
D
For a given shell,the penetration power of a subshell decreases from s to f, s > p > d > f.
Higher the penetration power, higher is the energy required to remove an electron.
Question 16. The second ionization potentials in electron volts of oxygen and fluorine atoms are respectively given by?
  1.    35.1, 38.3
  2.    38.3, 38.3
  3.    38.3, 35.1
  4.    35.1, 35.1
 Discuss Question
Answer: Option C. -> 38.3, 35.1
:
C
Second ionization potential is the energy required to remove an electron from a uni-positively charged ion.
Let's look at the electronic configurations.

O 2,6
O+ 2,5

F 2,7
F+ 2,6

I.P1
O O+ F F+
I.P2

O O2+ F+F2+
I.P1 of F>O as fluorine has smaller atomic size as compared to O.
I.P2 of O>F as O+ as it is harder to ionise the O+ compared to F+.
Question 17. Which one of the following is incorrect?
  1.    An element which has high electronegativity always has high electron gain enthalpy.
  2.    Electron gain enthalpy is the property of an isolated atom.
  3.    Electronegativity is the property of a bonded atom.
  4.    Both electronegativity and electron gain enthalpy are usually directly related to nuclear charge and inversely related to atomic size.
 Discuss Question
Answer: Option A. -> An element which has high electronegativity always has high electron gain enthalpy.
:
A
Elements with high electronegativity usually have high electron gain enthalpies, but this does not happen all the time.
If you take the example of nitrogen, it's electronegativity is one of the highest.
But if you look at its electron gain enthalpy, you actually need to supply energy to add the electron because nitrogen has a half-filled configuration which is stable.
Question 18. Arrange the following hydrides in their increasing acid strength [CH4, H2S, PH3 and SiH4] -
  1.    H2S
  2.    CH4
  3.    SiH4
  4.    CH4
 Discuss Question
Answer: Option B. -> CH4
:
B
As we go left to right in a period, as the non-metallic character increases and the acidic character of hydrides increases.
Question 19. For the processes K+(g) I K(g) IIK(g)
  1.    Energy is released in (I) and absorbed in (II)
  2.    Energy is absorbed in (I) and released in (II)
  3.    Energy is absorbed in both the processes
  4.    Energy is released in both the processes
 Discuss Question
Answer: Option A. -> Energy is released in (I) and absorbed in (II)
:
A
(I)K+(g)+eK(g) Negative electron gain enthalpy
(II)K(g)+eK(g) Positive electron gain enthalpy
In first process energy is released while in the second energy is absorbed.
Question 20. Representative elements belong to
  1.    s and p-block
  2.    p and d-block
  3.    f-block only
  4.    d and f-block
 Discuss Question
Answer: Option A. -> s and p-block
:
A
s and p-block elements expect inert gases are called representative elements as their valence electrons represent their group number

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