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12th Grade > Chemistry

IONIC EQUILIBRIUM MCQs

Total Questions : 30 | Page 3 of 3 pages
Question 21. Which of the following cannot act as Lewis base?
  1.    CH3NH2
  2.    H2O
  3.    BF3
  4.    NH3
 Discuss Question
Answer: Option C. -> BF3
:
C
BF3 has vacant orbital and incomplete octethence act as Lewis acid
Question 22. Arrhenius neutralization is described as
  1.    formation of water
  2.    proton transfer from acid to base
  3.    formation of dative bond
  4.    proton transfer from base to acid
 Discuss Question
Answer: Option A. -> formation of water
:
A
Net reaction of acid - base neutralization according to Arrhenius theory is formation of water
H++OHH2O
Question 23. At 25C, the dissociation constant of a base BOH is 1.0 × 1012. The 
concentration of Hydroxyl ions in 0.01 M aqueous solution of the base 
would be      
  1.    2.0 × 10−6molL−1
  2.    1.0 × 10−5molL−1
  3.    1.0 × 10−6molL−1
  4.    1.0 × 10−7molL−1
  5.    None of the options are correct.
 Discuss Question
Answer: Option D. -> 1.0 × 10−7molL−1
:
D
BOHB++OH
Initially,
BOH=C, B+ = 0 and OH = 0
At Equilibrium
BOH=CCα, B+ = Cα and OH = Cα
Kb=C2α2C(1α) = Cα2assuming α<<1; 1α 1
1012 = 102×α2; α2 = 1010; α= 105
OH = Cα = 0.01×105=107
Question 24. Which of the following is the best acceptor of proton ?
  1.    OH−
  2.    O−2
  3.    CH3−
  4.    NH3
 Discuss Question
Answer: Option C. -> CH3−
:
C
CH4 weakest acid among H2O, OH, CH4& NH3hence CH3is strongest base
Question 25. Which is the correct representation of the solubility product constant 
Ag2CrO4 of  
  1.    [Ag+]2[CrO2−4]
  2.    [Ag+][CrO2−4]
  3.    [2Ag+][CrO2−4]
  4.    [2Ag+]2[CrO2−4]
  5.    None of the options are correct.
 Discuss Question
Answer: Option A. -> [Ag+]2[CrO2−4]
:
A
Ag2CrO42[Ag+]+[CrO24]
Hence K[sp]=[Ag+]2+[CrO24]
Question 26. A monoprotic acid in 1.00 M solution is 0.01% ionised. The dissociation constant of this acid is 
  1.    1 × 10−8
  2.    1 × 10−4
  3.    1 × 10−6
  4.    1 × 10−5
  5.    None of the options are correct.
 Discuss Question
Answer: Option A. -> 1 × 10−8
:
A
K=α2C1α;α=0.01100
K=α2C=[0.01100]2×1=1×108
Question 27. The solubility of CaF2 is a moles/litre. Then its solubility product is ..... 
 
  1.    a2
  2.    4a3
  3.    3a2
  4.    a3
  5.    None of the options are correct.
 Discuss Question
Answer: Option B. -> 4a3
:
B
CaF2Ca2++2F;
KspforCaF2 = [Ca2+][F]2 = a×(2a)2=4a3
Question 28. Solubility product of a sulphide MS is 3 × 1025 and that of another sulphide 
NS is 4 × 1040. In ammonia solution 
  1.    Only NS gets precipitated
  2.    Only MS gets precipitated
  3.    No sulphide precipitates
  4.    Both sulphides precipitate
  5.    None of the options are correct.
 Discuss Question
Answer: Option D. -> Both sulphides precipitate
:
D
The concentration of S2ions in group II is lowered by maintaining acidic
medium in the presence of NH4Cl. The ionization of H2Sis supressed due
tocommon ion effect. So the ionic product is less than solubility product.
Question 29. Theory of ionization was given by 
  1.    Rutherford
  2.    Graham
  3.    Faraday
  4.    Arrhenius
  5.    None of the options are correct.
 Discuss Question
Answer: Option D. -> Arrhenius
:
D
Arrhenius proposed the theory of ionisation.
Question 30. The solubility of CaF2 is 2 × 104. Its solubilily product KSP is      
  1.    2 × 10−4
  2.    4 × 10−3
  3.    8 × 10−12
  4.    3.2 × 10−11
  5.    None of the options are correct.
 Discuss Question
Answer: Option D. -> 3.2 × 10−11
:
D
Ksp for CaF2=4s3=4×[2×104]3=3.2×1011

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