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Question
The  Kα x-ray emission line of tungsten occurs at λ = 21 pm. What is the energy difference between EK and EL levels in this atom (MeV refers to mega electron volts;1MeV = 106 eV and hc = 1242 eVnm)?
Options:
A .  0.59 MeV
B .  1.2 MeV
C .  59 KeV
D .  13.6 eV
Answer: Option A
:
A
Kαx-ray emission takes place when an electron jumps from L-shell to fill a vacancy created in K-shell.
Now EKis the energy of the atom when vacancy is in K-Shell, and ELIs the energy of the atom when vacancy is created in L-Shell. Also, EK >ELSo, when vacancy shifts from K to L, according to our agrument, the atomic energy decreases. How much ?
EKEL.
This difference results into X-ray photon.
Hence connecting the dots we can conclude that ; The energy difference between K and L levels is the energy of the photon.
Mathematically;
EKEL=Ephoton
Now,
EKEL=hcλ
Which gives after putting in the values;
EKEL=1242eVnm0.0021nm
Final calculations leads us to our answer;
EKEL=591428eV
Or,
EKEL=0.59MeV

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