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12th Grade > Chemistry

SURFACE CHEMISTRY MCQs

Total Questions : 30 | Page 3 of 3 pages
Question 21. Which of the following properties of colloids involve scattering of lights?
  1.    Colligative properties
  2.    Tyndall effect
  3.    Brownian movement
  4.    None of the above
 Discuss Question
Answer: Option B. -> Tyndall effect
:
B
The Tyndall effect is due to the fact that colloidal particles scatter light in all directions in space.
Question 22. Which of the following statement about zeolite is false?
  1.    They are used as cation exchangers
  2.    They have open structure which enables them to take up small molecules
  3.    Zeolites are aluminosilicates having three dimensional network
  4.    Some of the SiO4−4 units are repalced by AlO5−4 and AlO9−6- ions in zeolite
 Discuss Question
Answer: Option D. -> Some of the SiO4−4 units are repalced by AlO5−4 and AlO9−6- ions in zeolite
:
D
AlO54 ion has nearly the same size as the SiO44ion and can replace the latter from silicates provided electrical neutrality is maintained.
Question 23. 50 ml of 1 M oxalic acid is shaken with 0.5 gm of wood charcoal. The final concentration of the solution after adsorption is 0.2 M. Amount of oxalic acid absorbed per gm of charcoal is   (Use molar mass of hydrated oxalic acid = 126)
  1.    2.52 gm
  2.    6.30 gm
  3.    10.08 gm
  4.    None
 Discuss Question
Answer: Option C. -> 10.08 gm
:
C
Initially weight of oxalic acid present = W=126×1×501000=6.3gm
Finally weight of oxalic acid remaining = W=126×0.2×501000=6.35gm
0.5 gm of charcoal adsorbed 6.3×(115)=6.3×(45) gm of oxalic acid
So, amount of oxalic acid adsorbed per gram of charcoal =2×(6.3×(45))=10.08 gm
Question 24. A negatively charged suspension of clay in water is needed for precipitation of minimum amount of -
  1.    Aluminium chloride
  2.    Potassium sulphate
  3.    Sodium hydroxide
  4.    Hydrochloric acid
 Discuss Question
Answer: Option A. -> Aluminium chloride
:
A
A negatively charged clay suspension in water can be precipitated by minimum amount of Al3+(AlCl3)because Al3+ions have maximum opposite charge, i.e., +3 units
Question 25. For the most efficient functioning of enzymes which of the following statements is not correct
  1.    An optimum temperature is needed
  2.    An optimum pH is needed
  3.    They are substrate specific
  4.    They always increase activation energy
 Discuss Question
Answer: Option D. -> They always increase activation energy
:
D
Enzymes do not increase activation energy.
Question 26. Reactions in Zeolite catalysts depend on -
  1.    Pores
  2.    Apertures
  3.    Size of cavities
  4.    All of these
 Discuss Question
Answer: Option D. -> All of these
:
D
Zeolite is a shape-selective catalyst
Question 27. On the basis of data given below predict which of the following gases shows least adsorption on a definite amount of charcoal?
Gas Critical temp./K
CO2 304
SO2 630
CH4 190
H2 33
  1.    CO2
  2.    SO2
  3.    CH4
  4.    H2
 Discuss Question
Answer: Option D. -> H2
:
D
It has the least critical temperature
Question 28. The coagulation of 100ml of colloidal solution of gold is completely prevented by addition of 0.25g of a substance of X to it before adding 1ml of 10% NaCl solution. the gold number of "X" is-
  1.    0.25
  2.    25
  3.    250
  4.    2.5
 Discuss Question
Answer: Option B. -> 25
:
B
250 mg of X prevents coagulation of 100 ml of colloidal sol of gold. By definition gold number of X is taht amount of it in mg which prevents coagulation of 10 ml of colloidal gold sol. Hence, to prevent coagulation of 10ml of gold sol, the amount of X required =25 mg, which is the gold number of X.
Question 29. The role of a catalyst in a reversible reaction is to
  1.    Increase the rate of forward reaction
  2.    Decrease the rate of backward reaction
  3.    Alter the equilibrium constant of the reaction
  4.    Allow the equilibrium to be achieved quickly
 Discuss Question
Answer: Option D. -> Allow the equilibrium to be achieved quickly
:
D
An increase in rate of reaction in forward direction by a catalyst for a reaction in equilibrium brings in an increase in concentration of products and thus rate of backward reaction also increase to same magnitude and so allow the equilibrium to be achieved quickly.
Question 30. Which of the following forms cationic micelles above certain concentration?
  1.    sodium dedecylsulphate
  2.    cetyl trimethyl ammonium bromide
  3.    urea
  4.    sodium acetate
 Discuss Question
Answer: Option B. -> cetyl trimethyl ammonium bromide
:
B
Cetyl trimethyl ammonium cations aggregate to form cationic micelles.

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