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11th And 12th > Chemistry

SOLID STATE MCQs

Total Questions : 30 | Page 1 of 3 pages
Question 1.


Which of the following is not a characteristic properties of a solid state?


  1.     Definite shape
  2.     Incompressible
  3.     Large intermolecular distances
  4.     Fixed positions of the constituent particles
 Discuss Question
Answer: Option C. -> Large intermolecular distances
:
C

Following are the characteristic features of a solid state:


    I.            Definite shape, volume and mass


    II.           Intermolecular distances are short and intermolecular forces are strong


    III.          They are incompressible and rigid


    IV.          The constituent particles have fixed positions and can oscillate only about their mean positions


Question 2.


Which of the following are the characteristics of an amorphous solid?
A. Short range order
B. Sharp melting point
C. Isotropic in nature
D. Definite heat of fusion


  1.     A,D
  2.     A,C
  3.     A,C,D
  4.     B,D
 Discuss Question
Answer: Option B. -> A,C
:
B

Amorphous solids consist of particles of irregular shape, so it displays short range order.
Amorphous solids soften over a range of temperature, and hence doesn’t show sharp melting point.
The value of a physical property will be same from any directions in case of amorphous solids. So, they are said to be isotropic in nature.
Amorphous solids do not have a definite heat of fusion.


Question 3.


Which among the following solids are electrical insulators in solid state:


  1.     Polar molecular solids
  2.     Ionic solids
  3.     Non polar molecular solids
  4.     All of above
 Discuss Question
Answer: Option D. -> All of above
:
D

Polar and non-polar molecular solids are soft and non-conductors of electricity.
Ionic solids are non-conductors of electricity in solid state, as the constituent ions are not free to move (but in molten state or when dissolved in water the ions are free to move and hence they conduct electricity)


Question 4.


Choose the correct option:
  Crystal system Axial distanceAxial angles(a)Tetragonala=bcα=β=γ=90(b)Monoclinicabcα=γ=90β90(c)Rhombohedralab=cα=β=γ90(d)Triclinicabcαβγ90


  1.     a
  2.     b
  3.     c
  4.     d
 Discuss Question
Answer: Option C. -> c
:
C

Choose the correct option:
  Crystal system Axial distanceAxial angles(a)Tetragonala=bcα=β=γ=90(b)Monoclinicabcα=γ=90β90(c)Rhombohedrala = b = cα=β=γ90(d)Triclinicabcαβγ90


Question 5.


Na and Mg crystallize in BCC and FCC type crystals respectively, then the number of atoms of Na and Mg present in the unit cell of their respective crystal is


  1.     4 and 2
  2.     9 and 14
  3.     14 and 9
  4.     2 and 4
 Discuss Question
Answer: Option D. -> 2 and 4
:
D

The bcc cell consistes of 8 atoms at the corners and one atom at centre.
n=(8×18)+1=2
The fcc cell consists of 8 atoms at the eight corners and one atom at each of the six faces.This atom at the faces is shared by two unit cells.
n=8×18+(6×12)=4


Question 6.


What percentage of crystal space in fcc arrangement is vacant?


  1.     74%
  2.     32%
  3.     68%
  4.     26%
 Discuss Question
Answer: Option D. -> 26%
:
D

In face-centered cubic arrangement, 74% of the crystal space is filled



  •  Vacant space = 100 – 74 = 26%


Question 7.


A solid is made of two elements X and Z. The atoms Z are in CCP arrangement while the atom X occupy two-third of the tetrahedral sites. What is the formula of the compound?


  1.     XZ
  2.     XZ2
  3.     X4Z3 
  4.     X2Z3
 Discuss Question
Answer: Option C. -> X4Z3 
:
C

Tetrahedral sites are double compared to octahedral sites; and X is present in two-third of them


a)  So, ratio of X and Z equals 2×(23):1=4:3
formula of the compound = X4Z3 


Question 8.


Which among the following options give the correct relationship between the edge lengths ‘a’ and the radius of a sphere ‘r’ in a body-centered cubic structure.


  1.     a=34r
  2.     r=a22
  3.     r=34a 
  4.     r=a2
 Discuss Question
Answer: Option C. -> r=34a 
:
C

In EFD
b = a + a = 2a
Now in AFD
c2=a2+b2=a2+2a2=3a2
c=3a
The length of the body diagonal 'c' is equal to 4r, where r is the radius of the sphere (atom), as the three spheres along the diagonal touch each other.
Therefore, 3a=4r
a=4r3
r=34a
Which Among The Following Options Give The Correct Relations...


Question 9.


Assume a hypothetical cubic crystal lattice, named JEE-centered cubic (jcc) with the following characteristics:
I. An atom is present at all the corners of the cube
II. An atom is present at the center of two pairs of opposite faces
III. An atom is present at the center of all the edges of the cube
IV. One atom is present at its body-center
An element having the jcc lattice structure has a cell edge of 120 pm. The density of the element is 6.8 g/cm3. How many atoms are present in 408 g of the element?


  1.     1.73×1023
  2.     2.43×1023
  3.     2.43×1026 
  4.     1.73×1026
 Discuss Question
Answer: Option C. -> 2.43×1026 
:
C

Volume of unit cell =(120 pm)3=(120×1012)3m3=(123×1033)m3
Volume of 408 g of the element =massdensity=4086.8=60cm3=6×105m3
So, number of unit cells present in 408 g of the elements =6×105123×1033=3.472×1025 unit cells
Since each jcc unit cell consist of 7 atoms,
therefore the total number of atoms presents in 408 g of the given element
=7×3.472×1025=2.43×1026atoms


Question 10.


Question 11-12 is based on the following given information:
Assume a hypothetical cubic crystal lattice, named JEE-centered cubic (jcc) with the following characteristics:
I. An atom is present at all the corners of the cube
II. An atom is present at the center of two pairs of opposite faces
III. An atom is present at the center of all the edges of the cube
IV. One atom is present at its body-center
How many atoms are effectively present per unit cell in this hypothetical crystal lattice?


  1.     8
  2.     7
  3.     6
  4.     5
 Discuss Question
Answer: Option B. -> 7
:
B

    I.      8 corner atom ×(18) atom per unit cell = 1 atom


    II.     4 face-centered atoms ×(12) atom per unit cell = 2 atom


    III.    12 edge-centered atoms ×(14) atom per unit cell = 3 atom


    IV.     1 body centered atom × 1 atom per unit cell = 1 atom


So, Total number of atoms per unit cell =1+2+3+1=7 atoms


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