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11th And 12th > Chemistry

REACTION MECHANISM MCQs

Total Questions : 15 | Page 1 of 2 pages
Question 1.


Which of the following statements is incorrect for low reactivity of chloro benzene


  1.     Due to resonance
  2.     Polarity of C-X bond
  3.     sp2 hybridised state of C atom
  4.     Due to +E effect of Cl
 Discuss Question
Answer: Option D. -> Due to +E effect of Cl
:
D

Cl is involved in resonance as well as inductive effect and not in electrometric effect as it is more electronegative.


Question 2.


The product in the following reaction is
The Product In The Following Reaction Is


  1.    
  2.    
  3.    
  4.    
 Discuss Question
Answer: Option A. ->
:
A

The Product In The Following Reaction Is


Question 3.



  1.     I > II > III
  2.     II > I > III
  3.     II > III > I
  4.     III > II > I
 Discuss Question
Answer: Option C. -> II > III > I
:
C
The reactivity decreases in the order

Allylic > Secondary > primary.


Question 4.


The Reagent For The Above Conversion Is


The reagent for the above conversion is


  1.     Alcoholic KOH
  2.     Alcoholic KOH followed by  NaNH2
  3.     Aqueous KOH followed by NaNH2
  4.     Zn/ CH3COOH
 Discuss Question
Answer: Option B. -> Alcoholic KOH followed by  NaNH2
:
B

The Reagent For The Above Conversion Is


Question 5.


What is the order of reactivity of the following compounds towards nucleophilic substitution? What Is The Order Of Reactivity Of The Following Compounds T...


  1.     IV<III<II<I
  2.     IV<I<II<III
  3.     III<IV<II<I
  4.     II<IV<III<I
 Discuss Question
Answer: Option B. -> IV<I<II<III
:
B

The reactivity depends on the stability of the carbocation obtained upon ionization.  The order of stability is .


What Is The Order Of Reactivity Of The Following Compounds T...


 


Question 6.


The major product formed in the following reaction is :


The Major Product Formed In The Following Reaction Is :


  1.    
  2.    
  3.    
  4.    
 Discuss Question
Answer: Option C. ->
:
C

In protic solvent E2 proceeds over SN2.


Question 7.


The structure of the major product formed in the following reaction is
The Structure Of The Major Product Formed In The Following R...      


  1.    
  2.    
  3.    
  4.    
 Discuss Question
Answer: Option D. ->
:
D

Alkyl halides are more reactive than aryl halides, therefore the halogen present on the side chain is displaced.


Question 8.



  1.    
  2.    
  3.    
  4.    
 Discuss Question
Answer: Option D. ->
:
D

Question 9.


The order of decreasing nucleophilicity is


  1.     H2O>OH>CH3COO>CH3O
  2.     CH3COO>CH3O>HO>H2O
  3.     HO>CH3O>CH3COO>H2O
  4.     CH3O>OH>CH3COO>H2O
 Discuss Question
Answer: Option D. -> CH3O>OH>CH3COO>H2O
:
D

1. Due to the presence of -ve charge CH3O, OH,CH3COO , are more nucleophilic than H2O. Further due to + I effect of the CH3 group, CH3O is more nucleophilic than OH


2. CH3COO has the -ve charge on oxygen stabilized by resonance and therefore its nucloephilicity is less than those of CH3O and OH.


Question 10.


The rate of SN2 reaction is maximum when the solvent is


  1.     CH3OH
  2.     H2O
  3.     DMSO 
  4.     Benzene
 Discuss Question
Answer: Option C. -> DMSO 
:
C

Polar aprotic solvents such as DMSO increase the rate of the SN2 reaction.


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