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11th And 12th > Chemistry

IONIC EQUILIBRIUM MCQs

Total Questions : 30 | Page 1 of 3 pages
Question 1.


Which of the following is the strongest acid ? 


  1.     H2SO3
  2.     H2SO4
  3.     HClO4
  4.     H3PO4
 Discuss Question
Answer: Option C. -> HClO4
:
C

It is a HClO4


Question 2.


Which of the following is the strongest conjugate base


 


  1.     Cl
  2.     CH3COO
  3.     SO24
  4.     NO2
 Discuss Question
Answer: Option B. -> CH3COO
:
B

Because it is conjugate base of weak acid.


CH3COOH  CH3COO + H+


 


Question 3.


NaOH is a strong base because                      


  1.     It gives OH ion.
  2.     It can be oxidised 
  3.     It can be easily ionised
  4.     It provides H3O+ ions.
 Discuss Question
Answer: Option A. -> It gives OH ion.
:
A

NaOH completely dissociates to give Na+ and OH ions in water. Hence it is considered as a Strong base.


Question 4.


Review the equilibrium and choose the correct statement 


HClO4 + H2O  H3O+ + ClO4            


  1.     HClO4 is the conjugate acid of H2O
  2.     H3O+ is the conjugate base of H2O
  3.     H2O is the conjugate acid of H3O+
  4.     ClO4 is the conjugate base of HClO4
 Discuss Question
Answer: Option D. -> ClO4 is the conjugate base of HClO4
:
D

HClO4 + H2O  H3O+ + ClO4


Here HClO4 and ClO4 constitute conjugate acid and base pair.


Question 5.


Lewis acid


  1.     necessarily has H atoms.
  2.     Is a electron pair donor
  3.     Is always a proton donor
  4.     Is a electron pair acceptor
 Discuss Question
Answer: Option D. -> Is a electron pair acceptor
:
D

Lewis acids accept electron pairs


Question 6.


A white substance having alkaline nature in solution is 


  1.     NaNO3
  2.     NH4Cl
  3.     Na2CO3
  4.     Fe2O3
 Discuss Question
Answer: Option C. -> Na2CO3
:
C

Na2CO3 + 2H2O  2NaOH + H2CO3


Question 7.


Ammonium hydroxide is a weak base because 


  1.     It has low vapour pressure 
  2.     It is only slightly ionized  
  3.     It is not a hydroxide of any metal
  4.     It has low density
 Discuss Question
Answer: Option B. -> It is only slightly ionized  
:
B

It is a weak electrolyte since slightly ionized.


Question 8.


Equal volumes of 10%vv of HCl is mixed with 10%vv NaOH solution. If density pure NaOH is 1.5 times that of pure HCl then the resultant solution be


  1.     Basic
  2.     Neutral
  3.     Acidic
  4.     Can't be predicted
 Discuss Question
Answer: Option A. -> Basic
:
A

HCl = d


NaOH = 1.5 d


HCl in 10 ml of it = 10d36.5


NaOH in 10 ml of it  =10× 1.5d40= 15d40


NaOH> HCl


Question 9.


Which of the following is not a Lewis acid         


  1.     CO
  2.     SiCl4
  3.     SO3
  4.     Zn2+
 Discuss Question
Answer: Option A. -> CO
:
A

CO doesn't have a vacant d-orbital.


Question 10.


If α is the degree of ionization, C the concentration of a weak electrolyte and Ka the acid ionization constant, then the correct relationship between α, C and Ka  is


  1.     α2 = Ka × C.
  2.     α2 = CKa
  3.     α = KaC
  4.     α = CKa
 Discuss Question
Answer: Option C. -> α = KaC
:
C

According to the Ostwald's dilution formula α2  Ka(1  α)C. But for weak 


electrolytes α is very small. So that (1  α) can be taken as 1. So that α = KaC.


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