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12th Grade > Chemistry

D AND F BLOCK ELEMENTS MCQs

Total Questions : 43 | Page 5 of 5 pages
Question 41. The outer electronic configuration of Gd (Atomic No: 64) is:
  1.    4f8 5d0 6s2.
  2.    4f4 5d4 6s2.
  3.    4f7 5d1 6s2.
  4.    4f3 5d5 6s2.
 Discuss Question
Answer: Option C. -> 4f7 5d1 6s2.
:
C
Gadolinium (X64Gd)=[Xe]544f75d16s2.
Question 42. In context of the lanthanoids, which of the following statements is not correct?
  1.    All the members exhibit +3 oxidation state.
  2.    Because of similar properties the separation of lanthanoids is not easy.
  3.    Availability of 4f electrons results in the formation of compounds in +4 state for all the members of the series.
  4.    There is a gradual decrease in the radii of the members with increasing atomic number in the series.
 Discuss Question
Answer: Option C. -> Availability of 4f electrons results in the formation of compounds in +4 state for all the members of the series.
:
C
Availibilty of 4f electrons does not result in the formation of compounds in +4 oxidation state for all the members of the lanthanoid series.
Question 43. Which of the following arrangements does not represent the correct order of the property stated against it?
  1.    Sc
  2.    V2+ 
  3.    Ni2+ 
  4.    Co3+ 
 Discuss Question
Answer: Option B. -> V2+ 
:
B
Option a) – Number of oxidation states increases as we move from group 3 to group 7 in same period.
Option b) – V2+(3 unpaired electrons) %undefined Cr2+ ( 4 unpaired electrons) = Fe2+ (4 unpaired electrons) %undefined Mn2+ ( 5 unpaired electrons)
Option c)- Ionic size decreases from left to right in the same period.
Option d)- As the standard reduction potential value for the couple M3+/M2+ decreases, the stability of M3+ ion in aqueous solution increases. Thus, correct increasing order of stability of M3+ ions in aqueous solution is: Co3+ < Fe3+<Cr3+ <Sc3+.

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