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12th Grade > Chemistry

CHEMICAL BONDING MCQs

Total Questions : 30 | Page 3 of 3 pages
Question 21. Which of the following compounds does not have molecular plane as nodal plane for its π - electron cloud?
  1.    CH2 = CH2
  2.    C6H6
  3.    CH2 = C = CH2
  4.    All of the above
 Discuss Question
Answer: Option C. -> CH2 = C = CH2
:
C
Molecule is non-planar
Which Of The Following Compounds Does Not Have Molecular Pla...
Question 22. Which of the following deviates from the rest in geometry?
  1.    CH4
  2.    ClO4−1
  3.    SO4−2
  4.    BF3
 Discuss Question
Answer: Option D. -> BF3
:
D
BF3 is sp2 hybridised.
CH4, ClO41 and SO42​​​​​​​​​​​​​​ aresp3 hybridised.
Question 23. Hanny - Smith formula for calculating the percentage of ionic character is
  1.    16(|xA−xB|)+3.5(xA−xB)2
  2.    16(xA−xB)+3.5(xA−xB)2
  3.    16(xA−xB)2−3.5(xA−xB)
  4.    16(xA−xB)2+3.5(xA−xB)2
 Discuss Question
Answer: Option A. -> 16(|xA−xB|)+3.5(xA−xB)2
:
A
% ionic character = 16(|xAxB|)+3.5(xAxB)2
where 'xA ' is the electronegativity of one element and xB is the electronegativity of the other element.
The first expression includes a modulus because we are interested in thedifference in electronegativity.
Note: This gives the % ionic character. To calculate % covalentcharacter, we have to do 1 - (% ionic character).
Question 24. Highest viscosity is exhibited by :
  1.    Glycerol
  2.    Ethylene glycol
  3.    Ethanol
  4.    Water
 Discuss Question
Answer: Option A. -> Glycerol
:
A
Glycerol - a triol,formsmore hydrogen bonds
Question 25. Which of the following bond has the most polar character?
  1.    C - O
  2.    C - Br
  3.    C - F
  4.    C - S
 Discuss Question
Answer: Option C. -> C - F
:
C
Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons. The polar character depends on the electronegativity difference of the constituent atoms.
Since, carbon (C) is common among all options hence, the polar character of molecules will depend on the electronegativity of other atoms.
Fluorine is the most electronegative element. Hence, maximum electronegativity difference is seen in carbon and fluorine (C - F). Thus, the C-F bond has the most polar character.
Question 26. The increasing order of bond dissociation energies of C - C, C - H and H - H bonds is 
  1.    H - H < C - H < C - C
  2.    C - C < C - H < H - H
  3.    H - H < C - C < C - H
  4.    C - H < H - H < C - C
 Discuss Question
Answer: Option B. -> C - C < C - H < H - H
:
B
H - H bond energy is the highest due to s-s overlapping (exceptional case)
Question 27. The Correct Match Is
The correct match is
  1.    A - 1 - i
  2.    B - 3 - iv
  3.    C - 2 - ii
  4.    D - 4 - iii
 Discuss Question
Answer: Option C. -> C - 2 - ii
:
C
Pyramidal has three bond pair and one lone pair like NH3
Question 28. Incorrect set among the following
Molecule, Dipole moment, Geometry
  1.    NH3, μ=0, Trigonal pyramidal
  2.    H2O, μ≠0, Bent 
  3.    CHCl3, μ≠0, Tetrahedral
  4.    BCl3, μ=0, Trigonal planar
 Discuss Question
Answer: Option A. -> NH3, μ=0, Trigonal pyramidal
:
A
NH3 has dipole moment of 1.48D
Question 29. The hydrogen bond is shortest in
  1.    N - H .......O
  2.    F - H ...........O
  3.    N - H.........F
  4.    F - H ........F 
 Discuss Question
Answer: Option D. -> F - H ........F 
:
D
F is most electronegative atom
Question 30. The dipole moment of H - Br molecule is 2.6×1030 coulomb.metre. Its bond length is 1.3˚A Then, the percentage ionic character of H - Br bond is:
  1.    20%
  2.    16%
  3.    21.5%
  4.    12.5%
 Discuss Question
Answer: Option D. -> 12.5%
:
D
% of ionic character = dipole moment(observed)/ calculated value × 100
Calculated dipole moment = charge × distance, charge as you know is 1.6×1019 C

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