Question
2 mol of zinc is dissolved in HClat 25∘C. The work done in an open vessel is:
Answer: Option B
:
B
The following reaction takes place:
2Zn+4HCl→2ZnCl2+2H2
It is very impiortant to understand that this is an irreversible process since this reaction happens pretty quickly and hydrogengas escapes the system.
When H2 gas is liberated,it pushes back its surrounding and thus does some work against it.
Since it is an irreversible process, we can use the following equation:
W=PextΔV=−Pext(Vf−Vx)
Vi=0 thus ΔV=Vf
Vf=nRTPext
W=−Pext×nRTPext=−nRT
Given that n=2,R=8.314J/Kmol
T=25+273=298K
W=−2×8.314×298=4955.144J=4.955kJ
Tip: You can use approximations for R=25/3 and T=300 for quicker calculations!
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:
B
The following reaction takes place:
2Zn+4HCl→2ZnCl2+2H2
It is very impiortant to understand that this is an irreversible process since this reaction happens pretty quickly and hydrogengas escapes the system.
When H2 gas is liberated,it pushes back its surrounding and thus does some work against it.
Since it is an irreversible process, we can use the following equation:
W=PextΔV=−Pext(Vf−Vx)
Vi=0 thus ΔV=Vf
Vf=nRTPext
W=−Pext×nRTPext=−nRT
Given that n=2,R=8.314J/Kmol
T=25+273=298K
W=−2×8.314×298=4955.144J=4.955kJ
Tip: You can use approximations for R=25/3 and T=300 for quicker calculations!
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