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12th Grade > Chemistry

COORDINATION COMPOUNDS MCQs

Total Questions : 29 | Page 3 of 3 pages
Question 21. In the complex Fe(CO)x, the value of x is
  1.    3
  2.    4
  3.    5
  4.    6
 Discuss Question
Answer: Option C. -> 5
:
C
EAN = 36 so, 26 + 2 × n = 36
n = 5
Question 22. The ion which is not tetrahedral in shape is?
  1.    BF−4
  2.    NH+4
  3.    [Cu(NH3)4]2+
  4.    NiCl2−4
 Discuss Question
Answer: Option C. -> [Cu(NH3)4]2+
:
C
[Cu(NH3)4]2+ is square planar
Hybridazation state of Cu+2 is dsp2
Question 23. In a complex, the highest co-ordination number is
  1.    6
  2.    12
  3.    4
  4.    8
 Discuss Question
Answer: Option A. -> 6
:
A
According to Werner theory
Question 24. In which of the following complexes, nickel is in the highest oxidation state?
  1.    K4[Ni(CN)4]
  2.    [K2NiF6]
  3.    [Ni(CO)4]
  4.    [Ni(CN)4]2−
 Discuss Question
Answer: Option B. -> [K2NiF6]
:
B
Nickel has + 4 oxidation state.
Question 25. Which of the following metal ion is present in Ziegler-Natta catalyst?
  1.    Fe2+
  2.    Zr4+
  3.    Rh+1
  4.    Ti4+
 Discuss Question
Answer: Option D. -> Ti4+
:
D
This catalyst is made up of TiCl3+Al(C2H5)2Cl
Question 26. The Oxidation no. of Cr in [Cr(NH3)6]Cl3
  1.    8
  2.    6
  3.    4
  4.    3
 Discuss Question
Answer: Option D. -> 3
:
D
x + 6 × (0) + 3(–1) = 0
x = + 3
Question 27. Which of the following statement is incorrect ?
  1.    Co-ordination compounds and complexes are synonymous terms.
  2.    Complexes always give ions in solution.
  3.    Complexes may or may not give ions in solution
  4.    Complex ion does not dissociate into its compones even in solution.
 Discuss Question
Answer: Option B. -> Complexes always give ions in solution.
:
B
You can have complexes that do not form ions in solution.
e.g. [Fe(CO)5]
Question 28. The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is
  1.    [Cr(H2O)4(O2N)]Cl2
  2.    [Cr(H2O)Cl2]NO2
  3.    [Cr(H2O)4Cl(ONO)]Cl
  4.    [Cr(H2O)3Cl2(NO2)]H2O
 Discuss Question
Answer: Option B. -> [Cr(H2O)Cl2]NO2
:
B
Clis replaced by NO2in ionization sphere and are ionization isomers.
Question 29. Which of the following is a mixed salt?
  1.    CaOCl2
  2.    CuSO4.4NH3
  3.    AgCl.2NH3
  4.    PtCl4.5NH3
 Discuss Question
Answer: Option A. -> CaOCl2
:
A
Mixed salt contains two different types of cations or anions. It has Ca2+, it also contains two anions Cl and OCl.

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