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12th Grade > Chemistry

AMINES MCQs

Total Questions : 30 | Page 3 of 3 pages
Question 21. Identify incorrect statements among the following
I. Benzene diazonium chloride with hypophosphorous acid solution gives benzeneamine and phosphorous acid
II. Benzene diazonium chloride with phenol at PH> 7 gives yellow coloured dye
III. Benzene diazonium chloride with cuprous chloride and HCl gives chlorobenzene is called as Gattermann reaction
IV. Benzenediazonium chloride on hydrolysis with water at 100C gives phenol
  1.    All
  2.    I,III,IV
  3.    II,III only
  4.    I,II,III
 Discuss Question
Answer: Option D. -> I,II,III
:
D
With H3PO2 gives benzene, With phenol it gives orange dye ,III reaction is sandmeyer'sreaction
Question 22. In This Sequence, Incorrect Statement Is 
In this sequence, incorrect statement is 
  1.    'A' is phthalimide
  2.    C is methyl phathalimide
  3.    Formation of 'D' and 'E' from 'A' is Hoffmann bromamide reaction
  4.    Among the final products one of the product is 10amine
 Discuss Question
Answer: Option C. -> Formation of 'D' and 'E' from 'A' is Hoffmann bromamide reaction
:
C
A = Phthalimide; B= potassium salt of A ; C = N - methyl phthalimide D & E = Pot. Phthalate and methyl amine
Question 23. Which of the following is used as antioxidant in rubber industry
  1.    Schiff base
  2.    Schiff's reagent
  3.    Benzene diazonium chloride
  4.    Acetaldehyde ammonia
 Discuss Question
Answer: Option A. -> Schiff base
:
A
Condensation product of 10amine with aromatic aldehyde is used as antioxidant
Question 24. A mixture of three amines A, B and C is treated with Benzene sulphonyl chloride and filtered.' B' is obtained in the filterate. The mixture containing A and C is treated with KOH so that' A' becomes soluble while 'C' does not. Now A, B and C are
  1.    Aliphatic primary, secondary and tertiary
  2.    Aliphatic secondary, tertiary and primary
  3.    Aliphatic primary, tertiary and secondary
  4.    Aliphatic tertiary, secondary and primary
 Discuss Question
Answer: Option C. -> Aliphatic primary, tertiary and secondary
:
C
B is 30 amine as it is not reacting with benzene sulphonyl chloride; A is 10amine as theproduct is soluble in KOH; C is 20 amine
Question 25. The molecular formula of amine is C4H11N. Then ratio of 10, 20 and 30 isomeric amines possible are (structural isomers only)
  1.    4 : 3 : 2
  2.    4 : 3 : 1 
  3.    3 : 4 : 1
  4.    3 : 3 : 1
 Discuss Question
Answer: Option B. -> 4 : 3 : 1 
:
B
10 amines : CH3 - CH2 - CH2 - CH2 - NH2; (CH3)2CH - CH2 - NH2;
CH3 - CH2-CH(CH3) - NH2; (CH3)3C - NH2
30 amine: CH3 - CH2 - N(CH3)2
Question 26.
  1.    Negative catalyst in the decomposition of H2O2
  2.    Positive catalyst in the decomposition of H2O2
  3.    Antifreeze
  4.    Antichlor
 Discuss Question
Answer: Option A. -> Negative catalyst in the decomposition of H2O2
:
A
X = CH3COCl; Y = Acetanilide acts as preservative for H2O2
Question 27. Regarding benzene diazonium fluoroborate, correct statements are
A.Prepared from aniline by diazotization followed by treating the salt with HBF4
B.Fluorobenzene is obtained by direct fluorination of benzene with F2 gas
C.Unstable at room temperature and soluble in water
D.Stable at room temperature and insoluble in water
  1.    A & C
  2.    A & D
  3.    B & C
  4.    B & D
 Discuss Question
Answer: Option B. -> A & D
:
B
Direct fluorination of benzene is not possible
Question 28. Assertion (A): Sulphanilic acid exists as dipolar ion where as p - amino benzoic acid does not
Reason (R): Carboxy group being more acidic than - SO3H group can easily transfer a H+ to the amino group
  1.    A and R are true and R is the correct explanation of A
  2.    A and R are true and R is not the correct explanation of A
  3.    A is true, R is false
  4.    A is false, R is true
 Discuss Question
Answer: Option C. -> A is true, R is false
:
C
- SO3H is more acidic than - COOH group
Question 29. Which one of the following forms an alcohol with nitrous acid solution at 00C
  1.    Aniline
  2.    Ethyl methyl amine
  3.    Dimethyl amine
  4.    Ethyl amine
 Discuss Question
Answer: Option D. -> Ethyl amine
:
D
Aliphatic 10amine gives N2 gas with nitrous acid and alcohol
Question 30. Which of the following shows carbyl amine reaction
A. Aniline                          B. Ethyl methyl amine
C. Tertiary butyl amine     D. Isopropyl amine
The correct answer is 
  1.    A, B, C, D
  2.    B, C
  3.    A, D
  4.    A, C, D
 Discuss Question
Answer: Option D. -> A, C, D
:
D
'B' is 20amine

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