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Question
An element A in a compound ABD has oxidation number A n-. It is oxidised by Cr2O27 in acidic medium. In the experiment 1.68×103 x moles ofK2Cr2O7 were used for 3.26×103 moles of ABD. The new oxidation number of A after oxidation is:
Options:
A .  3
B .  3-n
C .  n-3
D .  +n
Answer: Option B
:
B
First - let us write down the reaction:
Cr2O27+AnBDCr3++An+x
From stoichiometry, we have:
Equivalents ofCr2O27 = equivalents of ABD
1.68×103=3.26×103×x
Solving, we get x=3.
Hence, the new oxidation number is: 3-n

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