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A typical dorm room or bedroom contains about 2500 moles of air. Find the change in the internal energy of this much air when it is cooled from 35.0C to 26.0C at a constant pressure of 1.00 atm. Treat the air as an ideal gas with γ = 1.400.
Options:
A .  4.68 × 105 J
B .  5.14 × 104 J
C .  −4.68 × 105 J
D .  −5.14 × 104 J
E .  along the line CD
Answer: Option C
:
C
The change in internal energy ΔEint=nCVΔT. We need to obtain CV from the given information. Now,
γ=[CPCV], and, CPCV=R
γ=[CV+RCV]=[1+RCV]
RCV=γ1
CV=[Rγ1]
Therefore,
ΔEint=nCVΔT
=2500×(8.3141.41)×(2635)J
=4.68×105J.
It's a negative change, meaning the internal energy has decreased with cooling, which is consistent with theory. In fact, if an AC had to do this cooling, its job would be take 4.68×105Jfrom the internal energy in the air and dump it outside. This will be dealt with in greater detail when we study the second law of thermodynamics.

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