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12th Grade > Chemistry

S BLOCK ELEMENTS MCQs

Total Questions : 30 | Page 1 of 3 pages
Question 1. Potassium when heated strongly in oxygen, it forms
  1.    K2O
  2.    KO2
  3.    K2O2
  4.    KO3
 Discuss Question
Answer: Option B. -> KO2
:
B
Whenever potassium is heated strongly in a good supply of air or oxygen, it forms KO2. KO2 is superoxide.
K2O is obtained by heating potassium nitrate with potassium.
Controlled oxidation of potassium in excess air or oxygen at 300
Question 2. Halides of alkaline earth metals form hydrates such as MgCl2.6H2O,CaCl2.6H2O, BaCl2.2H2O and SrCl2.2H2O. This shows that halides of group 2 elements
  1.    Are hygroscopic in nature
  2.    Can act as dehydrating agents
  3.    Can absorbs moisture from air
  4.    All of the above
 Discuss Question
Answer: Option D. -> All of the above
:
D
The tendency to form hydrates decreases in the group. All the options reflect the fact that the chlorides do form hydrates.
Question 3. When chloro - bridged dimeric form of beryllium chloride is heated at 1200C, then in the product is formed, hybridization of central atom & shape of molecule is
  1.    sp2 , angular
  2.    sp3, pyramidal
  3.    sp, linear
  4.    sp2, triangular shape
 Discuss Question
Answer: Option C. -> sp, linear
:
C
It becomes monomer above 1200C. The monomer is a linear molecule with sp hybridization.
Question 4. Look at the following reaction:
LiH+AlH3LiAlH4
Here AlH3 and LiH act as:
  1.    Lewis acid and Lewis base
  2.    Lewis base and Lewis acid
  3.    Bronsted base and Bronsted acid
  4.    None of these
 Discuss Question
Answer: Option A. -> Lewis acid and Lewis base
:
A
Look At The Following Reaction:LiH+AlH3⟶LiAlH4Here AlH3 a...
As shown in the figure, the central metal atom in AlH3 has only six valence electrons. Hence, it could accept a pair of electrons (Lewis acid) to complete its octet. On the other hand, H is a Lewis base because it has two valence electrons thus having a completely filled shell. Further, since the ion readily shares or donates electrons - it acts as a Lewis base.
Question 5. Statement-1 : Alkali metals dissolve in liquid ammonia to give blue solutions.
Statement-2 : Alkali metals in liquid ammonia give solvated species of the type [M(NH3)n]+ (M =alkali metals).
  1.    Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1.
  2.    Statement-1 is True, Statement-2 is True; Statement-2 is Not a correct explanation for Statement-1
  3.    Statement-1 is True, Statement-2 is False
  4.    Statement-1 is False, Statement-2 is True
 Discuss Question
Answer: Option B. -> Statement-1 is True, Statement-2 is True; Statement-2 is Not a correct explanation for Statement-1
:
B
Alkali metals dissolve in liquid ammonia giving deep blue solutions which are conducting in nature. The blue colour of the solution is due to ammoniated electrons which absorb energy in the visible region of light. The second statement describes the solvated cations (positively charged species) whereas the colour is due to the solvated electrons. Do note howeverthat both the statements are accurate.
Question 6. The correct order of thermal stability of alkali metal hydrides is:
  1.    CsH>RbH>KH>NaH>LiH
  2.    LiH>NaH>KH>RbH>CsH
  3.    CsH>NaH>KH>RbH>LiH
  4.    LiH>KH>NaH>RbH>CsH
 Discuss Question
Answer: Option B. -> LiH>NaH>KH>RbH>CsH
:
B
The stability of alkali metal hydrides decreases with increase in the size of the metal cation. In other words, as we go down the group - the stabilityof the hydrides decreases.
Question 7. NaH reacts with water to give:
  1.    Alkaline solution
  2.    NH3 gas
  3.    Acidic solution
  4.    Neutral solution
 Discuss Question
Answer: Option A. -> Alkaline solution
:
A
NaH+H2ONaOH+H2(g)
As you can see - we get NaOH which is very strongly basic.
Question 8. The correct order of density of alkali metals is:
 Discuss Question
Answer: Option A. -> Alkaline solution
:
A
As we go down a group - density increases generally. However, there is a notable exception in potassium, which is less dense than sodium. Simply put, in the case of potassium the increase in shell size outweighs the pull of the core on the outer shell electron and so potassium is less dense than sodium.
Question 9.
  1.    Paramagnetic, paramagnetic
  2.    Paramagnetic, diamagnetic
  3.    Diamagnetic, paramagnetic
  4.    Diamagnetic ,diamagnetic
 Discuss Question
Answer: Option A. -> Paramagnetic, paramagnetic
:
A
X is NO2& Y is O2 .Both the species have unpaired electrons in their electronic configurations (For O2 you will have to use MOT).
Due to the presence of unpaired electrons, both NO2 and O2 are paramagnetic.
Question 10. The reaction of sodium is highly exothermic with H2O. The rate of reaction is lowered by 
  1.    Lowering the temperature
  2.    Mixing with alcohol
  3.    Mixing with acetic acid
  4.    Making an amalgam
 Discuss Question
Answer: Option D. -> Making an amalgam
:
D
Sodium amalgam, commonly denoted Na(Hg), is analloyofmercuryandsodium.
Na(Hg) is less reactive than Na. It will decrease the rate of reaction.
Sodium is highly reactive with water and decreasing the temperature does not decrease the rate of the reaction if we consider
Le Chatelier's principle.
Sodium reacts with alcohol and acetic acid also. They will not affect the rate of reaction of sodium with water.

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