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The boiling point of methanol, water and dimethyl ether are respectively 650 C, 1000 C and 34.50 C. Which of the following best explains these wide variations in b.p.?


Options:
A .   The molecular mass increases from water (18) to methanol (32) to diethyl ether (74)
B .   The extent of H-bonding decreases from water to methanol while it is absent in ether
C .   The extent of intramolecular H-bonding decreases from ether to methanol to water
D .   The density of water is 1.00 g ml1, methanol 0.7914 g ml1 and that of diethyl ether is 0.7137 g ml1
Answer: Option B
:
B

Water has strongest hydrogen bond of the three



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