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Question
A solution of urea contains 8.6 gm/litre (mol. Wt. 60.0). It is isotonic with a 5% (W/W) solution of a non-volatile solute having density 1 g/cc. The molecular weight of the solute will be          
Options:
A .  348.8
B .  34.88
C .  3488
D .  861.2
Answer: Option A
:
A
Isotonic solutionshavesameosmoticpressure
As Osmotic pressure = C R T
C1=C2
n1V1=n2V2
5% W/W solutionmeans 100g ofsolution contains 5gofsolute
8.6601=5M1001000
M=5×60×108.6=348.8

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